Textbook Question
Based on Hooke's law, choose the bond in each pair that you expect to vibrate at a higher wavenumber.
(f) C―S vs C=O
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15. Analytical Techniques:IR, NMR, Mass Spect
Infrared Spectroscopy
3:41 minutesProblem 15b
Textbook Question
Choose the bond in each pair that you expect to vibrate at the higher wavenumber.
(b) C―H vs. C―O
Verified step by step guidance1
Understand that the wavenumber in infrared (IR) spectroscopy is related to the frequency of vibration of a bond. The wavenumber is inversely proportional to the mass of the atoms involved and directly proportional to the bond strength.
Recall that lighter atoms and stronger bonds tend to vibrate at higher frequencies, resulting in higher wavenumbers.
Consider the atomic masses: Hydrogen (H) is lighter than Oxygen (O), so C―H bonds involve a lighter atom compared to C―O bonds.
Evaluate the bond strengths: C―H bonds are generally stronger than C―O bonds due to the higher electronegativity difference and shorter bond length.
Conclude that the C―H bond will vibrate at a higher wavenumber than the C―O bond because it involves a lighter atom and a stronger bond.
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Video duration:
3mKey Concepts
Here are the essential concepts you must grasp in order to answer the question correctly.
Bond Vibrational Frequency
Bond vibrational frequency refers to the energy required for a bond to stretch or compress during vibration. It is influenced by the mass of the atoms and the strength of the bond. Lighter atoms and stronger bonds typically vibrate at higher frequencies, resulting in higher wavenumbers in infrared spectroscopy.
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Mass of Atoms
The mass of the atoms involved in a bond affects its vibrational frequency. Lighter atoms, such as hydrogen, contribute to higher vibrational frequencies compared to heavier atoms like oxygen. This is because lighter atoms can move more easily, requiring less energy to vibrate, thus increasing the wavenumber.
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Bond Strength
Bond strength is a measure of how strongly two atoms are held together in a molecule. Stronger bonds, such as C-H, typically vibrate at higher frequencies than weaker bonds like C-O. This is due to the greater energy required to stretch or compress a stronger bond, leading to higher wavenumbers in spectroscopic analysis.
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