Drawing on what you know about the stereochemistry of alkene addition reactions,
b. predict the configuration of the product of the reaction.

For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (viii) Cl₂ (1 equiv.). If you expect two products, show both.

(c)

For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (ix) Br₂ (2 equiv.). If you expect two products, show both.

(c)

Trans addition is heavily favored for the addition of Br₂ and Cl₂ to alkynes. With chlorination, however, more of the syn addition product is formed. Rationalize this fact in light of your answer to Assessments 10.50 and 10.51.

Drawing on what you know about the stereochemistry of alkene addition reactions,

a. write the mechanism for the reaction of 2-butyne with one equivalent of Br₂.

Show how hex-1-yne might be converted to

d. 1,1,2,2-tetrabromohexane.

Predict the product(s) that would result when the alkenes shown here are allowed to react under the following conditions: (v) 1. Hg(OAc)₂ , H₂O 2. NaBH₄

(b)

Predict the products you would get when the following alkenes react under the following conditions: (i) H₂SO₄, H₂O and (ii) 1. Hg(OAc)₂, H₂O , 2. NaBH₄

(d)

For the alkynes shows here, show the product(s) expected to form when treated under the following conditions: (ix) Br₂ (2 equiv.). If you expect two products, show both.

(f)