Eliminate incorrect options: The first option, 'A circular arrangement of amino acids forming a ring structure,' describes a cyclic peptide, which is not the same as a peptide chain. The second option, 'A single amino acid with a modified side chain,' refers to an individual amino acid, not a chain. The third option, 'A group of amino acids with similar side chain properties,' describes a classification based on side chain characteristics, not a peptide chain.