- 1. Draw the structure of cis-CH3CH=CHCH2CH3 showing the pi bond with its proper geometry. 2. Draw the trans isomer, and circle the coplanar atoms. Are there still six?
Problem 1
Problem 1a
If a hydrocarbon has nine carbon atoms, three double bonds, and one ring, how many hydrogen atoms must it have?
Hint: If you prefer to use a formula, elements of unsaturation = 1/2(2C + 2 - H)
C = number of carbons
H = number of hydrogens
Problem 1b
Calculate the number of elements of unsaturation implied by the molecular formula C6H12.
Hint: If you prefer to use a formula, elements of unsaturation = 1/2(2C + 2 - H)
C = number of carbons
H = number of hydrogens
Problem 1c
Give five examples of structures with this formula (C6H12). At least one should contain a ring, and at least one should contain a double bond.
Hint: If you prefer to use a formula, elements of unsaturation = 1/2(2C + 2 - H)
C = number of carbons
H = number of hydrogens
Problem 2
Determine the number of elements of unsaturation in the molecular formula C4H6. Give all nine possible structures having this formula. Remember that
a double bond = one element of unsaturation
a ring = one element of unsaturation
a triple bond = two elements of unsaturation
Problem 3a
Draw five more compounds of formula C4H6NOCl.
Problem 4a,b,c
For each of the following molecular formulas, determine the number of elements of unsaturation, and draw three examples.
a. C4H4Cl2
b. C4H8O
c. C6H8O2
Problem 4d,e
For each of the following molecular formulas, determine the number of elements of unsaturation, and draw three examples.
d. C5H5NO2
e. C6H3NClBr
Ch. 7 - Structure and Synthesis of Alkenes; Elimination